Issue 23, 1974

X-Ray structures of [Cr2(CO)6(AsMe)9] and [Mo2(CO)6(AsPrn)8]: the stabilisation of an As9 ring and an As8 chain by co-ordination

Abstract

The compound [Cr2(CO)6(AsMe)9] contains a nine-membered As ring co-ordinated to each Cr atom through three As atoms while [Mo2(CO)6(AsPrn)8] contains a chain of eight As atoms with terminal As atoms bridging both metal atoms and one other arsenic atom in the chain also co-ordinated to each metal, together with an Mo–Mo bond.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 953-954

X-Ray structures of [Cr2(CO)6(AsMe)9] and [Mo2(CO)6(AsPrn)8]: the stabilisation of an As9 ring and an As8 chain by co-ordination

P. S. Elmes, B. M. Gatehouse, D. J. Lloyd and B. O. West, J. Chem. Soc., Chem. Commun., 1974, 953 DOI: 10.1039/C39740000953

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