Issue 20, 1974

An oxidative addition reaction of trans-[IrCl(N2)(Ph3)2] in which the dinitrogen ligand is retained in the co-ordination sphere of the product

Abstract

trans-Chlorodinitrogenbis(triphenylphosphine) iridium(I) undergoes an oxidative addition reaction with methyl trifluoromethane-sulphonate to give a new dinitrogen complex of iridium(III) with a very high ν(N [triple bond, length half m-dash] N) stretching frequency.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 815-816

An oxidative addition reaction of trans-[IrCl(N2)(Ph3)2] in which the dinitrogen ligand is retained in the co-ordination sphere of the product

D. M. Blake, J. Chem. Soc., Chem. Commun., 1974, 815 DOI: 10.1039/C39740000815

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