Single-crystal X-ray analysis has shown that in dehydrated divalent copper-exchanged faujasite the so-called site III-type cations are located at the pore entrances to the supercage and are effectively bonded to only one framework oxygen, thus being present in a highly unsaturated co-ordination geometry.
I. E. Maxwell and J. J. De Boer, J. Chem. Soc., Chem. Commun., 1974, 814 DOI: 10.1039/C39740000814
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