Base hydrolysis of the Ru(NH3)53+ complex of acetonitrile to the corresponding complex of the acetamide anion occurs with a rate ca. 108 as fast as the free ligand, ca. 106 as fast as the analogous RuII complex, and more than 102 faster than the RhIII analogue.
A. W. Zanella and P. C. Ford, J. Chem. Soc., Chem. Commun., 1974, 795 DOI: 10.1039/C39740000795
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