Hasubanonine (1) and protostephanine (2) are shown by tracer experiments to be biosynthesised from two different C6–C2 units, one being the amine (22); many possible advanced precursors are synthesised and tested.
A. R. Battersby, R. C. F. Jones, R. Kazlauskas, C. Poupat, C. W. Thornber, S. Ruchirawat and J. Staunton, J. Chem. Soc., Chem. Commun., 1974, 773 DOI: 10.1039/C39740000773
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