The ratio of desulphurisation to deoxygenation of oxophosphoranesulphenyl chlorides, >P(O)SCI, by trivalent phosphorus compounds depends on the nature of the PIII compounds and is accompanied by inversion of configuration at the chiral phosphorus atom of the sulphenyl chloride.
B. Krawiecka, J. Michalski, J. Mikolajczak, M. Mikołajczyk, J. Omelańczuk and A. Skowrońska, J. Chem. Soc., Chem. Commun., 1974, 630 DOI: 10.1039/C39740000630
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