Reaction of the title chloromethylpyrimidine with potassium hydrosulphide yields a sulphur-bridged 1,3-diazepin-2-one; in contrast, reaction with various amines give rise to α-aminopyrrolines and controlled reaction with hydroxide an α-hydroxypyrroline.
J. Ashby and D. Griffiths, J. Chem. Soc., Chem. Commun., 1974, 607 DOI: 10.1039/C39740000607
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