Ab initio molecular orbital theory indicates that barriers to rotation about the Cα–Cβ bond in several ethyl radicals with β first row substituents are considerably smaller than in the corresponding cations.
L. Radom, J. Paviot, J. A. Pople and P. v. R. Schleyer, J. Chem. Soc., Chem. Commun., 1974, 58b DOI: 10.1039/C3974000058B
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