Issue 14, 1974

Synthesis and X-ray structure of tri-µ-carbonyl-bis-(1,2-diphenyl-3,4-di-t-butylcyclobutadiene)di-iron

Abstract

Irradiation of 1,2-diphenyl-3,4-di-t-butylcyclobutadienetricarbonyliron (1) gives the new complex, (C24H28)2Fe2(CO)3 which, from X-ray data, appears to contain an iron-iron triple bond [Fe–Fe = 2·177(3)Å].

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 563-564

Synthesis and X-ray structure of tri-µ-carbonyl-bis-(1,2-diphenyl-3,4-di-t-butylcyclobutadiene)di-iron

S. Murahashi, T. Mizoguchi, T. Hosokawa, I. Moritani, Y. Kai, M. Kohara, N. Yasuoka and N. Kasai, J. Chem. Soc., Chem. Commun., 1974, 563 DOI: 10.1039/C39740000563

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