The reaction of sulphinyl chlorides with achiral alcohols in the presence of optically-active tertiary amines has been found, by means of 1H n.m.r. spectroscopy using a chiral europium complex, to give optically-active sulphinates with optical purity up to 45%.
M. Mikołajczyk and J. Drabowicz, J. Chem. Soc., Chem. Commun., 1974, 547 DOI: 10.1039/C39740000547
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