Issue 14, 1974
From the journal:

Journal of the Chemical Society, Chemical Communications

Preparation and X-ray crystal structure of a novel tetranuclear copper(I) ethylenethiourea cluster complex, µ4-ethylenethiourea-cyclo-tetrakis-µ-(ethylenethiourea)tetrakis[ethylenethioureacopper(I)] nitrate hexahydrate

Alvin L. Crumbless,   Lawrence J. Gestaut,   Randall C. Rickard  and  Andrew T. McPhail  

Abstract

The structure, geometry, and bonding in [Cu4(C3H6N2S)9(NO3)4],6H2O have been established by X-ray analysis which reveals discrete Cu4(C3H6N2S)94+ cations containing an alternating Cu–S eight-membered ring with a unique ethylenethiourea ligand in an axial position bridging four copper atoms.

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Article information

DOI
https://doi.org/10.1039/C39740000545
Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 545-546

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Preparation and X-ray crystal structure of a novel tetranuclear copper(I) ethylenethiourea cluster complex, µ4-ethylenethiourea-cyclo-tetrakis-µ-(ethylenethiourea)tetrakis[ethylenethioureacopper(I)] nitrate hexahydrate

A. L. Crumbless, L. J. Gestaut, R. C. Rickard and A. T. McPhail, J. Chem. Soc., Chem. Commun., 1974, 545 DOI: 10.1039/C39740000545

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