Stereoselective introduction of the methoxycarbonyl group into the tetrahydrofluoren-9-one (1) giving the 9β-methoxycarbonyl derivative (5) has been achieved in high yield.
Y. Yamada, K. Hosaka, H. Nagaoka and K. Iguchi, J. Chem. Soc., Chem. Commun., 1974, 519 DOI: 10.1039/C39740000519
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