The base catalysed rearrangement of catechol mono-allyl ethers (1) and (4) at 78° involves successive sigmatropic rearrangements to give products that differ from those obtained by sigmatropic rearrangements under normal Claisen conditions.
W. D. Ollis, R. Somanathan and I. O. Sutherland, J. Chem. Soc., Chem. Commun., 1974, 494 DOI: 10.1039/C39740000494
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