The crystal and molecular structure of a dioxygen adduct of [Co(CN)5]3– has been determined, the complex is best formulated as a nearly linear superoxide complex of CoIII with a Co–O–O angle of 175°.
L. D. Brown and K. N. Raymond, J. Chem. Soc., Chem. Commun., 1974, 470 DOI: 10.1039/C39740000470
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