It is shown that by considering the 13C–C–C–H coupling constant between the α-CO2– and the β-protons in amino-acids it is possible to obtain side-chain conformational information concerning the rotamer populations which is not available from studies of H–H coupling constants alone.
J. Feeney, P. E. Hansen and G. C. K. Roberts, J. Chem. Soc., Chem. Commun., 1974, 465 DOI: 10.1039/C39740000465
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