Issue 11, 1974
From the journal:

Journal of the Chemical Society, Chemical Communications

Stoicheiometric hydrogenation of olefins using HRuCl(PPh3)3 and formation of an ortho-metallated ruthenium(II) complex

Brian R. James,   Larry D. Markham  and  Daniel K. W. Wang  

Abstract

Stoicheiometric hydrogenation of olefins using HRuCl(PPh3)3 in the absence of hydrogen results in formation of the dimer [(Ph3P)ClRu(o-C6H4PPh2)]2; this complex reacts with H2, and HCl, to yield in solution the catalytically important bisphosphine complexes RuXCl(PPh3)2(X = H, Cl).

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Article information

DOI
https://doi.org/10.1039/C39740000439
Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 439-440

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Stoicheiometric hydrogenation of olefins using HRuCl(PPh3)3 and formation of an ortho-metallated ruthenium(II) complex

B. R. James, L. D. Markham and D. K. W. Wang, J. Chem. Soc., Chem. Commun., 1974, 439 DOI: 10.1039/C39740000439

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