Barriers to pyramidal inversion of directly bonded three-co-ordinate atoms exhibit an interdependence which is determined principally by the differences in the electronegativities of these atoms; thus the phosphorus inversion barrier in H2NPH2 is higher than that in PH3.
I. G. Csizmadia, A. H. Cowley, M. W. Taylor and S. Wolfe, J. Chem. Soc., Chem. Commun., 1974, 432 DOI: 10.1039/C39740000432
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