Issue 10, 1974

Cycloaddition reactions of cyclic and acyclic 1,3-dipoles with diphenylcyclopropenone and related compounds. A new rearrangement

Abstract

Cycloaddition of mesoionic compounds with diphenylcyclopropen-one and -thione, and tosylimino- and dicyanomethylene-cyclopropene occurs across the endocyclic C[double bond, length half m-dash]C double bond, whereas cycloaddition of benzonitrile oxide with diphenylcyclopropenone occurs across the C[double bond, length half m-dash]O double bond to give triphenyl-1,3-oxazin-6-one by a new type of rearrangement.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 412-413

Cycloaddition reactions of cyclic and acyclic 1,3-dipoles with diphenylcyclopropenone and related compounds. A new rearrangement

H. Matsukubo and H. Kato, J. Chem. Soc., Chem. Commun., 1974, 412 DOI: 10.1039/C39740000412

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