Cycloaddition reactions of cyclic and acyclic 1,3-dipoles with diphenylcyclopropenone and related compounds. A new rearrangement
Abstract
Cycloaddition of mesoionic compounds with diphenylcyclopropen-one and -thione, and tosylimino- and dicyanomethylene-cyclopropene occurs across the endocyclic C
C double bond, whereas cycloaddition of benzonitrile oxide with diphenylcyclopropenone occurs across the C
O double bond to give triphenyl-1,3-oxazin-6-one by a new type of rearrangement.
Please wait while we load your content...