Issue 10, 1974

Stereochemistry of C-1 hydrogen exchange in the interconversion of trans,trans- and cis,trans-farnesols by soluble enzymes from tissue cultures of Andrographis paniculata

Abstract

When a cell-free system from A. paniculata tissue cultures isomerises trans,trans-farnesol (tt-F) to cis,trans-farnesol (ct-F), the 1-pro-R hydrogen of tt-F is retained and the 1-pro-S hydrogen lost; by contrast, conversion of ct-F proceeds with retention of the 1-pro-S and loss of the 1-pro-R hydrogen of ct-F.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 385-386

Stereochemistry of C-1 hydrogen exchange in the interconversion of trans,trans- and cis,trans-farnesols by soluble enzymes from tissue cultures of Andrographis paniculata

K. H. Overton and F. M. Roberts, J. Chem. Soc., Chem. Commun., 1974, 385 DOI: 10.1039/C39740000385

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements