Whereas, reaction of [Rh(ButNC)4]+ with primary amines affords diaminocarbene complexes, the reaction of [RhR1(X)(ButNC)4]+(R1= alkyl, X = halogen or ButNC) or [RhR1C(NHR2)(NHBut)(ButNC)3]+ with primary amine R2NH2 gives chelated dicarbene complexes.
P. R. Branson, R. A. Cable, M. Green and M. K. Lloyd, J. Chem. Soc., Chem. Commun., 1974, 364 DOI: 10.1039/C39740000364
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