The rate of nitronium ion formation is the rate-determining step in the nitration of toluene with mixed acid under certain conditions, and values of the rate constant have been determined for the first time.
J. W. Chapman and A. N. Strachan, J. Chem. Soc., Chem. Commun., 1974, 293 DOI: 10.1039/C39740000293
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