Contrary to previous reports the stereoselectivity of the deuteriation of enamines is low and is indicative of a reactant-like transition state; enol ethers show a greater preference for axial deuterium incorporation.
P. W. Hickmott and K. N. Woodward, J. Chem. Soc., Chem. Commun., 1974, 275 DOI: 10.1039/C39740000275
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