N.m.r. coalescence phenomena, unambiguously related to inversion of configuration at selenium and tellurium, have been observed for the first time in complexes of the type (Et2X)2Pt(Hal)2(X = Se or Te); palladium analogues display similar characteristics.
R. J. Cross, T. H. Green and R. Keat, J. Chem. Soc., Chem. Commun., 1974, 207 DOI: 10.1039/C39740000207
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