An associative mechanism is postulated for Me2Y (Y = S, Se, Te) exchange for TaCl5,Me2Y in non-co-ordinating solvents on the basis of the kinetic dependence, activation energies, and steric effects; the reaction centre exerts some discrimination between different nucleophiles.
R. Good and A. E. Merbach, J. Chem. Soc., Chem. Commun., 1974, 163 DOI: 10.1039/C39740000163
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