Reaction of LiCuMe2 at low temperature with LiAlH4 in diethyl ether results in the formation of a highly pyrophoric solid whose analysis is consistent with the formula LiCuH2, and which is stable as an etherate.
E. C. Ashby, T. F. Korenowski and R. D. Schwartz, J. Chem. Soc., Chem. Commun., 1974, 157 DOI: 10.1039/C39740000157
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