The existence of octahedral solvates of the Al3+ cation with trimethyl phosphate, dimethyl methyl-phosphonate, and dimethyl phosphite and a tetra-hedral solvate of hexamethylphosphoramide, is shown by their 27Al n.m.r. spectra in nitromethane.
Jean-J. Delpuech, M. R. Khaddar, A. Peguy and P. Rubini, J. Chem. Soc., Chem. Commun., 1974, 154 DOI: 10.1039/C39740000154
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