Addition of carbenes CR21(R1= COMe, CO2Me, or CO2Et) to aliphatic and cyclic sulphides to yield sulphonium ylides was highly selective, whereas the addition of nitrenes NR2(R2=p-MeC6H4SO2 or CO2Et) to give iminosulphuranes was quite unselective.
D. C. Appleton, D. C. Bull, J. McKenna, J. M. McKenna and A. R. Walley, J. Chem. Soc., Chem. Commun., 1974, 140 DOI: 10.1039/C39740000140
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