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An unusual dimeric structure with tetragonally co-ordinated copper(II) ions, bridged by oxime groups into six-membered rings, has been found for CuLCIO4·H2O, where L represents the anion of 2-(2-hydroxyethyl)imine-3-oximatobutane; the low magnetic moment per copper atom (0·25 B.M.) results from superexchange coupling through the bridge.
J. A. Bertrand, J. H. Smith and P. G. Eller, J. Chem. Soc., Chem. Commun., 1974, 95 DOI: 10.1039/C39740000095
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