Phosphorus-31 hyperfine splittings in tetraphenylporphyrincobalt(II) complexes with Et3P and (EtO)3P and the corresponding dioxygen complexes are used in evaluating the influence of substituents on the nature of the phosphorus σ-donor orbital.
B. B. Wayland and M. E. Abd-Elmageed, J. Chem. Soc., Chem. Commun., 1974, 61 DOI: 10.1039/C39740000061
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