Reactions of propynylplatinum(II) compounds
Abstract
The alkynylplatinum(II) compounds trans-Pt-(C
CR)2L2 and trans-PtCl(C
CR)L2(R
Me or CF3; L
PMe2Ph) show interesting chemistry based on reaction at either the organic or inorganic site of unsaturation; a new synthesis of alkoxy-carbene ligands and evidence for platinum-stabilized carbonium ion intermediates are reported.
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