The N-methyl signal of 1,8-bisdimethylaminonaphthalene (1) separates into a doublet at –120°, while for 1-benzylmethylamino-8-dimethylaminonaphthalene (2) a different process causes non-equivalence of the NMe2 and CH2Ph groups below –8°. The nature of these processes is discussed and barriers are reported.
R. W. Alder and J. E. Anderson, J. Chem. Soc., Perkin Trans. 2, 1973, 2086 DOI: 10.1039/P29730002086
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