Issue 12, 1973

The solvolytic fragmentation of trialkoxy-2-halogenoethylsilanes

Abstract

Trialkoxy-2-halogenoethylsilanes decompose in alkaline solution to give ethylene by a hydroxide ion-catalysed reaction, whereas in acid solutions these compounds undergo rapid hydrolysis to 2-halogenoethylsilanetriols which then undergo fragmentation by both uncatalysed and hydroxide ion-catalysed reactions.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1973, 1699-1702

The solvolytic fragmentation of trialkoxy-2-halogenoethylsilanes

M. J. Gregory, J. Chem. Soc., Perkin Trans. 2, 1973, 1699 DOI: 10.1039/P29730001699

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