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Kinetic and product analyses indicate that 1,2-diaryl-2-[aryl(methyl)amino]vinyl arenesulphonates react in dry ethanol via a rate-limiting heterolysis of the sulphur–oxygen bond to generate sulphinate anions and carbonyl derivaties. The behaviour in other solvolytic media is also briefly discussed.
A. Burighel, G. Modena and U. Tonellato, J. Chem. Soc., Perkin Trans. 2, 1973, 1021 DOI: 10.1039/P29730001021
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