The synthesis of hexaflourodesmosrerol (VIII) by a witting condensation between a sterodial triphenylphonium ylide and hexafluoroacetone is described. The 24,25 double bond structure (VIII) is resistant to hydrigenation over palladium and to hydroboration.
J. E. Herz and S. C. Montalvo, J. Chem. Soc., Perkin Trans. 1, 1973, 1233 DOI: 10.1039/P19730001233
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