The gas phase i.r. and liquid phase Raman spectra of the phosphines (CF3)2PX (X = H, F, Cl, Br, I) have been recorded, and the observed fundamentals assigned on the basis of Cs symmetry. Coupling of the vibrational modes of the same symmetry class has been noted.
R. C. Dobbie and B. P. Straughan, J. Chem. Soc., Dalton Trans., 1973, 2754 DOI: 10.1039/DT9730002754
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