The reaction of orthovanadate, VO43–, with excess of acid had been shown to follow at least two pathways. Very rapid reactions lead to the formation of an unknown intermediate together with a small and non-reproducible amount of decavanadate. Both the intermediate and the decavanadate are then degraded to the final product, VO2+.
B. W. Clare, D. L. Kepert and D. W. Watts, J. Chem. Soc., Dalton Trans., 1973, 2476 DOI: 10.1039/DT9730002476
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