The i.r. and electronic spectra and magnetic properties of a range of Group VIB metal thiolates, M(SR)3[M = Mo or W; R = Me, Et, Bu, or Ph] are reported. It is concluded that these compounds probably have polymeric chain structures with metal–metal interaction occurring between adjacent octahedra.
D. A. Brown, W. K. Glass and C. O'Daly, J. Chem. Soc., Dalton Trans., 1973, 1311 DOI: 10.1039/DT9730001311
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