Issue 10, 1973

The conformation of triphenylbismuthine and tris-(p-chlorophenyl)bismuthine in benzene solution

Abstract

Molar Kerr constant, dipole moment, and dielectric relaxation measurements of (p-C6H4Cl)3Bi in benzene solution indicate a C–Bi–C bond angle of 93 ° and an average rotation (in the same sense) of each C6H4Cl group about its C–Bi bond of 45° from a model in which the aromatic planes intersect along the symmetry axis. A similar configuration in solution is likely in the case of Ph3Bi, for which a C–Bi–C bond angle of 94° has been reported in the solid state.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1973, 1101-1102

The conformation of triphenylbismuthine and tris-(p-chlorophenyl)bismuthine in benzene solution

J. W. Hayes, D. J. Millar, D. V. Redford and J. D. Saxby, J. Chem. Soc., Dalton Trans., 1973, 1101 DOI: 10.1039/DT9730001101

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