The reduction of cerium(IV)(monomer, type B) by hydrogen peroxide has been studied in 1 M-HClO4 and found to be rapid. A slower reaction observed previously is now believed to be most probably due to traces of cerium(IV)(polymer, type A) which reacts only slowly with hydrogen peroxide.
A. Samuni and G. Czapski, J. Chem. Soc., Dalton Trans., 1973, 487 DOI: 10.1039/DT9730000487
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