Issue 2, 1973

Three-co-ordinated transition-metal compounds. Part II. Electronic spectra and magnetism of tris(bistrimethylsilylamido)derivatives of scandium, titanium, vanadium, chromium, and iron

Abstract

The electronic spectra, magnetic susceptibilities, and preliminary e.s.r. data are reported for the trigonal compounds M[N(SiMe3)2]3 where M = Sc, Ti, V, Cr, and Fe. The data are interpreted on the basis of crystal-field calculations for dn systems in D3h symmetry.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1973, 185-191

Three-co-ordinated transition-metal compounds. Part II. Electronic spectra and magnetism of tris(bistrimethylsilylamido)derivatives of scandium, titanium, vanadium, chromium, and iron

E. C. Alyea, D. C. Bradley, R. G. Copperthwaite and K. D. Sales, J. Chem. Soc., Dalton Trans., 1973, 185 DOI: 10.1039/DT9730000185

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