The spin exchange between the cobalt(II) ions in the diamagnetic modification of (PhNC)4CoI2 is achieved through a strictly linear Co–I–Co bridge; the compound crystallizes as µiodo-bis[iodotetrakis(phenylisocyanide)cobalt(II)] iodide, [I–Co(L)4–I–Co(L)4–I]+I–(L = PhNC).
D. Baumann, H. Endres, H. J. Keller and J. Weiss, J. Chem. Soc., Chem. Commun., 1973, 853b DOI: 10.1039/C3973000853B
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