Examination of the exchange reactions between isobutane and deuterium, and n-butane and deuterium on alumina has revealed that the reactive hydrocarbon intermediates possess carbanionic character.
P. J. Robertson, M. S. Scurrell and C. Kemball, J. Chem. Soc., Chem. Commun., 1973, 799a DOI: 10.1039/C3973000799A
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