Issue 9, 1973
From the journal:

Journal of the Chemical Society, Chemical Communications

Stabilisation of metals in a low co-ordinative environment using the bis(trimethylsilyl)methyl ligand; coloured SnII and PbII alkyls, M[CH(SiMe3)2]2

Peter J. Davidson  and  Michael F. Lappert  

Abstract

(Me3Si)2CHLi and SnCl2 in ether at 0° give Sn[CH(SiMe3)2]2, which is diamagnetic at room temperature and behaves chemically as a singlet ‘stannylene’, yielding complexes such as R2SnM′(CO)5(M′= Cr or Mo).

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Article information

DOI
https://doi.org/10.1039/C3973000317A
Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 317a-317a

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Stabilisation of metals in a low co-ordinative environment using the bis(trimethylsilyl)methyl ligand; coloured SnII and PbII alkyls, M[CH(SiMe3)2]2

P. J. Davidson and M. F. Lappert, J. Chem. Soc., Chem. Commun., 1973, 317a DOI: 10.1039/C3973000317A

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