Issue 22, 1973

Isotope effects in E2 transition states with non-linear proton abstraction

Abstract

Calculations show that E2 transition states in which the base, β-hydrogen and β-carbon forms a right or acute angle give β-deuterium isotope effects substantially smaller than those normally found experimentally.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 850-851

Isotope effects in E2 transition states with non-linear proton abstraction

W. H. Saunders, J. Chem. Soc., Chem. Commun., 1973, 850 DOI: 10.1039/C39730000850

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