Issue 21, 1973

Direct observation of an isolated state in the ion C2F6+: a violation of the quasi-equilibrium theory of mass spectra

Abstract

It is shown on the basis of photoelectronphotoion coincidence measurements, that ions in the first excited state of C2F6+ decompose without prior internal conversion into the ground state, thus violating a basic assumption of the quasi-equilibrium theory of mass spectra.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 832-833

Direct observation of an isolated state in the ion C2F6+: a violation of the quasi-equilibrium theory of mass spectra

I. G. Simm, C. J. Danby and J. H. D. Eland, J. Chem. Soc., Chem. Commun., 1973, 832 DOI: 10.1039/C39730000832

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