Issue 19, 1973

Bridging cycloheptatrienyl complexes: X-ray crystal structure of [Ru2(CO)5(SiMe3)(C7H6SiMe3)]

Abstract

Cycloheptatrienes, 7-RC7H7, react with [Ru(CO)4(SiMe3)]2 to afford inter alia fluxional complexes [Ru2(CO)5(SiMe3)(C7H6R)](R = H, Me, Ph, C6F5); an X-ray structural study on a minor product form C7H8 reveals ring substitution by a trimethylsilyl group.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 727-728

Bridging cycloheptatrienyl complexes: X-ray crystal structure of [Ru2(CO)5(SiMe3)(C7H6SiMe3)]

A. Brookes, J. Howard, S. A. R. Knox, V. Riera, F. G. A. Stone and P. Woodward, J. Chem. Soc., Chem. Commun., 1973, 727 DOI: 10.1039/C39730000727

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