Issue 19, 1973

The optical activity of achiral molecules in a cholesteric solvent

Abstract

In a cholesteric solvent molybdenum hexacarbonyl and other optically-isotropic molecules give Cotton effects which are due to the differential effective Lorentz radiation field for left and right circular light, arising from the large circular birefringence of the medium.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 712-713

The optical activity of achiral molecules in a cholesteric solvent

S. F. Mason and R. D. Peacock, J. Chem. Soc., Chem. Commun., 1973, 712 DOI: 10.1039/C39730000712

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