The average geometrical structures of CH(NO2)3 and CCl(NO2)3 are consistent with C3 models having similar parameters for C–N, N![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
O, and ONO, and different ones for ∠ NCN; the C–Cl bond length for the tetrahedral carbon atom in CCl(NO2)3(1·712 Å) is the shortest yet found.
N. I. Sadova, N. I. Popik, L. V. Vilkov, A. Pankrushev and V. A. Shlyapochnikov, J. Chem. Soc., Chem. Commun., 1973, 708 DOI: 10.1039/C39730000708
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