Issue 17, 1973

Addition of singlet and triplet silylene to buta-1,3-diene

Abstract

Formation of high-energy silicon atoms by the nuclear recoil technique in the presence of buta-1,3-diene gives rise to silylene consisting of 80% triplet and 20% singlet; both configurations add to buta-1,3-diene to give silacyclopent-3-ene.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 637-638

Addition of singlet and triplet silylene to buta-1,3-diene

G. P. Gennaro, Y. Su, O. F. Zeck, S. H. Daniel and Y. Tang, J. Chem. Soc., Chem. Commun., 1973, 637 DOI: 10.1039/C39730000637

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