The reactivities of RhCI(PPh3)3, RhCl(PPh3)2, and Rh2Cl2(PPh3)4 toward H2, and the contributions of each of these species to the overall rate of hydrogenation of RhCl(PPh3)3 in solution, have been determined; RhCl(PPh3)2 is at least 104 times as reactive as the other two species.
J. Halpern and C. S. Wong, J. Chem. Soc., Chem. Commun., 1973, 629 DOI: 10.1039/C39730000629
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